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She has a well-deserved reputation for being very caring and sympathetic, and always tries to go the extra mile to help a friend in need, so you're not surprised that she's trying to do all that she can to help him cope with his unpleasant divorce. When they emerged from the bedroom a couple of hours later your wife held his hand as she walked him to the door, and then gave him a kiss and told him that any time he felt the least bit lonely he should know he was always welcome to stop by. You have a feeling he's going to be stopping by pretty often.
After you went to bed, your friend helped your wife clean up after the party.